Carbon paste electrodes, modified with 5,6,14,15-dibenzo-1,4-dioxa-8,12-diazacyclopentadeca-5,14-diene containing different ligating atoms of oxygen and nitrogen, have been employed for the voltammetric determination of Ag(¥°) ion from aqueous solution. The voltammetric response was characterized with respect to paste composition, preconcentration method, kind of anion, variation of pH, Ag(¥°) ion concentration, and possible interferences. Linear calibration curves were obtained for Ag(¥°) ion concentration ranging from 3.0¡¿10-^6M to 8.0¡¿10-^5M, and detection limit was 8.5¡¿10-^7M.
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